Dual photo/thermal initiation with charge transfer complexes based on bromide‐based electron acceptors
نویسندگان
چکیده
Different combinations of donors and acceptors charge transfer complexes (CTCs) can realize visible light catalysis in multiple wavelength bands. Here, we successfully demonstrated that 2-bromoacetophenone as an electron acceptor, combined with amines (for formation CTC), achieve photopolymerization under [email protected] nm irradiation, initiating the polymerization (meth)acrylates, induction time be completely eliminated by condition optimization. The CTC was also shown to have dual photo/thermal initiation capability eventually applied 3D printing well.
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ژورنال
عنوان ژورنال: Journal of polymer science
سال: 2023
ISSN: ['1542-9385', '0098-1273']
DOI: https://doi.org/10.1002/pol.20220642